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What temperature is NBR vs FKM?

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Understanding the Temperature Ranges of NBR and FKM

When selecting materials for various industrial applications, it is crucial to understand their properties, including their temperature resistance. Two commonly used elastomers in industries are NBR (Nitrile Butadiene Rubber) and FKM (Fluoroelastomer). Each of these materials has distinct temperature ranges and properties that make them suitable for different applications. This article will delve into the temperature ranges of NBR and FKM, comparing their characteristics and typical uses.

NBR (Nitrile Butadiene Rubber)

NBR, also known as Buna-N or nitrile rubber, is a synthetic rubber copolymer of acrylonitrile (ACN) and butadiene. It is widely used due to its excellent resistance to oils, fuels, and other chemicals. NBR's temperature resistance is one of its key characteristics, making it suitable for various applications.

Temperature Range of NBR

NBR can typically withstand temperatures ranging from -40°C to +120°C (-40°F to +248°F). However, the exact temperature range can vary depending on the specific formulation and the proportion of acrylonitrile in the polymer. Higher acrylonitrile content generally improves oil resistance but can reduce flexibility at lower temperatures.

In general, NBR is suitable for applications where moderate temperature resistance is required, along with good resistance to petroleum-based oils and fuels. It is commonly used in automotive, aerospace, and industrial applications, including fuel hoses, gaskets, seals, and O-rings.

Limitations of NBR

While NBR offers good resistance to oils and fuels, it has limitations in terms of temperature resistance. At temperatures above 120°C (248°F), NBR can begin to degrade, losing its mechanical properties and becoming brittle. Additionally, NBR is not suitable for applications involving exposure to ozone, sunlight, or weathering, as it can crack and deteriorate under these conditions.

FKM (Fluoroelastomer)

FKM, commonly known by the brand name Viton, is a type of fluoroelastomer that contains fluorine atoms. It is known for its exceptional resistance to high temperatures, chemicals, and environmental factors. FKM is often used in demanding applications where other elastomers would fail.

Temperature Range of FKM

FKM can typically withstand temperatures ranging from -20°C to +200°C (-4°F to +392°F), with some specialized grades capable of handling even higher temperatures up to 250°C (482°F). This wide temperature range makes FKM suitable for applications involving extreme temperatures, both hot and cold.

The high-temperature resistance of FKM is due to the strong carbon-fluorine bonds in its molecular structure. These bonds provide excellent thermal stability, allowing FKM to maintain its properties even at elevated temperatures. Additionally, FKM exhibits good low-temperature flexibility, although it is not as flexible as some other elastomers at very low temperatures.

Applications of FKM

Due to its superior temperature resistance and chemical stability, FKM is used in a wide range of demanding applications. These include:

  • Automotive: FKM is used in fuel system seals, gaskets, and O-rings, where high-temperature resistance and chemical compatibility with fuels and oils are essential.

  • Aerospace: FKM is used in aircraft fuel systems, hydraulic systems, and engine components, where it must withstand extreme temperatures and aggressive chemicals.

  • Industrial: FKM is used in chemical processing, oil and gas, and power generation industries for seals, gaskets, and hoses that must resist high temperatures and harsh chemicals.

Limitations of FKM

While FKM offers excellent temperature and chemical resistance, it has some limitations. It is more expensive than other elastomers, such as NBR, which can be a consideration in cost-sensitive applications. Additionally, FKM may not perform as well as other elastomers in low-temperature applications, where its flexibility can be reduced.

Comparison of NBR and FKM

When comparing NBR and FKM, it is essential to consider the specific requirements of the application. Here are some key points of comparison:

  • Temperature Range: NBR has a temperature range of -40°C to +120°C (-40°F to +248°F), while FKM can withstand temperatures from -20°C to +200°C (-4°F to +392°F) or higher. FKM is the better choice for high-temperature applications.

  • Chemical Resistance: Both NBR and FKM offer good resistance to oils and fuels, but FKM provides superior resistance to a broader range of chemicals, including aggressive solvents and acids.

  • Cost: NBR is generally more cost-effective than FKM, making it suitable for applications where budget constraints are a consideration.

  • Environmental Resistance: FKM offers better resistance to ozone, sunlight, and weathering compared to NBR, making it suitable for outdoor and harsh environmental conditions.

  • Low-Temperature Flexibility: NBR offers better low-temperature flexibility compared to FKM, making it suitable for applications involving cold temperatures.

Conclusion

In summary, both NBR and FKM have unique properties that make them suitable for different applications. NBR is an excellent choice for applications requiring moderate temperature resistance and good oil and fuel resistance at a lower cost. On the other hand, FKM is ideal for high-temperature applications and environments involving aggressive chemicals and harsh conditions. Understanding the temperature ranges and properties of these elastomers can help in selecting the right material for specific industrial needs.

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